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Stainless Steel Basics #2

So, in our last post we briefly introduced Stainless Steel (SS) in general overview; We introduced the grades most common to general industry (304 and 316), and we looked at some of the properties of those grades.

There are, however, many grades of Stainless, each with its own strengths and weaknesses and economies. It is my feeling that due to overall education of the pros and cons of many of these grades, and lack of familiarity, many grades of stainless are used inappropriately in the maintenance arena. So many grades, so many mechanical forces, so many types of corrosion. (Variables relating to corrosive conditions alone are nearly infinite). One grade of stainless may be working in a particular application, but that may be only relative to other materials that have worked less effectively. So, let’s begin by getting acquainted with the benefits various grades may afford.

Two important things to keep in mind are; A specific grade, perfect for your application, may exist but may not be available in the form needed (tube, sheet, plate, bar). The grade may exist and be available, but, due to limitations in fabrication, may not readily lend itself to the configuration of your part.

Most often used, Type 304 and 316, fairly economical, good general corrosion resistance, elevated temperature resistant, and somewhat user ambivalent to a bit combative.
(Consider grade 303, if machining speed is a serious consideration, which is generally not the case in maintenance situations). These grades are austenitic 18-8 type, non-magnetic, will work-harden, but do not respond to thermal hardening.

Commonly used when increased strength is required; 410 and 416. Note that 416 is 410 modified for ease of machining. Superior to 304 and 316 in Sour Service Applications. (Martensitic, magnetic, responds to heat treating.)

Persistent problems, not addressed by either of the two groups listed above, will require consideration of modified, or enhanced grades. Those grades will involve modifications to element content (increasing content of elements, such as Nickel, Moly, Nitrogen, etc). Expect increases in cost. Among these are non-galling grades (such as Nitronic grades, Mir50), elevated temperature grades (such as 309 and 330), and a host of trade named products that are relatively economical and effective. Then there are, what I like to refer to as “The Exotics”; the next level up. Exotic in chemistry, and exotic in cost. Cost is of course relative to benefit; however, too often exotic materials are selected in an express leap to the ultimate solution. Generally, once that selection is made, the user is committed to a cycle of selecting grades equal or superior to that grade. Assumptions being, the grade in use is the minimum required grade. Going forward, service-life needs to be improved; Current service-life never being assumed to be the best-case scenario.

Modified grades may already be numerically identified (AISI SAE, UNS, etc.). Often, those targeting specific maintenance conditions, will be identified by a Trade-Name, identifying the producer. That producer will issue guidance on their trade named grades, to insure they are correctly applied in the field.

IMPORTANT CONSIDERATIONS:
As you add to the chemistry and increase corrosion resistance, strength, and toughness, etc.,
you are creating a product that fights and resists forces that attack the part in service. Read that as a product that “Does not play well with others.” Keep in mind that when you need to work with it, it may not play well with you either. It may solve the problem in service, but you will have to get it into service first.

Pay close attention to “User Friendly” stainless. How does it machine? How weldable is it? Does it tend to gall? Does it move? Then take a second look at your part. User friendly stainless may be a bit of an oxymoron, but it can be as important as the ultimate in-service performance.

-Howard Thomas, November 18th, 2022

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Stainless Steel – The Very Basics

THE 300 SERIES OF STAINLESS STEEL

If a steel has more than 10 ¾% Chromium content, it is classified as a type of Stainless Steel. There are many types (grades) of Stainless Steel, just as there are many types of corrosion. One grade of stainless steel may work well with one type of corrosion and then be terrible for service in another type of corrosion. The most common stainless grade is 304. Modify it a bit (improve) and you get 316. Enhance that a little, and you get 317. If you add Sulphur to type 304 stainless, you get 303 stainless, which is a “Free-machining grade”. Note: Generally, as you add elements to stainless steel to improve machinability, or strength, you may lessen strength and service-life.

Three hundred series grades are often referred to as; 18-8 stainless; where the 18 stands for percent of chromium content and 8 refers to the percent Nickel content. Those grades have some commonalities; grain structure of Austenite, non-magnetic, not generally responsive to thermal hardening, ability to work-harden.

Steel that has an Austenitic grain structure is not hardenable by heat treatment, but it is hardenable by cold working. Austenitic stainless grades are non-magnetic; i.e. they won’t, under general conditions, attract a magnet.
Strain-hardening, Cold-drawing, Cold-Finished, Cold-working, and Work-hardening, are all pretty much synonyms. Bang it around, Squash it, or keep bending it back and forth and it’s going to get harder; sometimes near 50RC hard.

18-8 Types of stainless steel are popular (common) for good reason. They are excellent for many applications exposed to corrosion, and they are readily available from suppliers. There are of course limitations imposed by various specific types of corrosion as well as limitations imposed by physical characteristics of the actual parts required (strength, straightness, etc). We will explore those in later posts.

 

-Howard Thomas, October 17th, 2022

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Availability

Are you able to find the particular material, grade, size and shape, by conducting a simple web-search? Availability will be influenced by many factors. Let’s assume the adage; “If you got the money and the time, you can probably get it.” is still very true. But since most often general plant maintenance is the last rung on the “Exotic Metals Food Chain”, most of us will not have the money nor the time. The global state of the raw materials, usage, cost, geography, political climate, shape, size, and condition, and perhaps most importantly, the minimum required order size required. Not necessarily in that order.

During WWII, nickel (considered one of the key ingredients in stainless steel) was in short supply and was being rationed. Metallurgical engineers discovered that they could recreate stainless grades, with similar properties by substituting cheaper elements, like manganese and nitrogen for the more expensive nickel. It was a case of: “live with a little less performance from these modified grades or, have no stainless at all.”

Similarly, a screw machine shop driven by production, speed, and cost, may specify free-machining grades of stainless for which they are willing to sacrifice a bit of performance for processing speed. Those grades may have been treated by adding a mineral element that allows the tooling to pass through the steel more easily than would be possible with a non-treated grade. The addition of that mineral may not contribute to the strength or corrosion resistance or weldability of the steel. It has been added simply to promote machinability. In fact, the addition may diminish other key properties of the steel. Recent innovations have developed free-machining grades that still have high mechanical properties. Note that treated grades may only exist in the form that is used by the most screw machine shops. Such as bar only, no sheet or plate.

-Howard Thomas, October 4th 2017

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