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So, in our last post we briefly introduced Stainless Steel (SS) in general overview; We introduced the grades most common to general industry (304 and 316), and we looked at some of the properties of those grades.

There are, however, many grades of Stainless, each with its own strengths and weaknesses and economies. It is my feeling that due to overall education of the pros and cons of many of these grades, and lack of familiarity, many grades of stainless are used inappropriately in the maintenance arena. So many grades, so many mechanical forces, so many types of corrosion. (Variables relating to corrosive conditions alone are nearly infinite). One grade of stainless may be working in a particular application, but that may be only relative to other materials that have worked less effectively. So, let’s begin by getting acquainted with the benefits various grades may afford.

Two important things to keep in mind are; A specific grade, perfect for your application, may exist but may not be available in the form needed (tube, sheet, plate, bar). The grade may exist and be available, but, due to limitations in fabrication, may not readily lend itself to the configuration of your part.

Most often used, Type 304 and 316, fairly economical, good general corrosion resistance, elevated temperature resistant, and somewhat user ambivalent to a bit combative.
(Consider grade 303, if machining speed is a serious consideration, which is generally not the case in maintenance situations). These grades are austenitic 18-8 type, non-magnetic, will work-harden, but do not respond to thermal hardening.

Commonly used when increased strength is required; 410 and 416. Note that 416 is 410 modified for ease of machining. Superior to 304 and 316 in Sour Service Applications. (Martensitic, magnetic, responds to heat treating.)

Persistent problems, not addressed by either of the two groups listed above, will require consideration of modified, or enhanced grades. Those grades will involve modifications to element content (increasing content of elements, such as Nickel, Moly, Nitrogen, etc). Expect increases in cost. Among these are non-galling grades (such as Nitronic grades, Mir50), elevated temperature grades (such as 309 and 330), and a host of trade named products that are relatively economical and effective. Then there are, what I like to refer to as “The Exotics”; the next level up. Exotic in chemistry, and exotic in cost. Cost is of course relative to benefit; however, too often exotic materials are selected in an express leap to the ultimate solution. Generally, once that selection is made, the user is committed to a cycle of selecting grades equal or superior to that grade. Assumptions being, the grade in use is the minimum required grade. Going forward, service-life needs to be improved; Current service-life never being assumed to be the best-case scenario.

Modified grades may already be numerically identified (AISI SAE, UNS, etc.). Often, those targeting specific maintenance conditions, will be identified by a Trade-Name, identifying the producer. That producer will issue guidance on their trade named grades, to insure they are correctly applied in the field.

IMPORTANT CONSIDERATIONS:
As you add to the chemistry and increase corrosion resistance, strength, and toughness, etc.,
you are creating a product that fights and resists forces that attack the part in service. Read that as a product that “Does not play well with others.” Keep in mind that when you need to work with it, it may not play well with you either. It may solve the problem in service, but you will have to get it into service first.

Pay close attention to “User Friendly” stainless. How does it machine? How weldable is it? Does it tend to gall? Does it move? Then take a second look at your part. User friendly stainless may be a bit of an oxymoron, but it can be as important as the ultimate in-service performance.

-Howard Thomas, November 18th, 2022

If memory serves, I did a post on Lean Duplex some time ago. It is an important grade of stainless and worth a revisit.

Basically, Lean Duplex is a leaner chemistry derivative of Duplex Stainless Steel. Duplex Stainless Steel is recognized as having a unique shared grain structure; Austenite and Ferrite. Each of those grain types contributes to the characteristics and performance of the steel grade. The grade was developed to provide resistance to Stress Corrosion Cracking (SCC), a type of corrosive failure prevalent in SOUR SERVICE applications in operations such as Refineries and Pulp & Paper plants. Sour Service applications involve acidic or base (alkaline) exposure. 2205 Duplex is probably the most common grade of Duplex that the industry is familiar with; although there are several others. I refer to 2205 as the “Original Grade”.

The short and sweet history of steel usage to combat SCC in sour service maintenance applications is this: 304 and 316 (Austenitic grain) worked tolerably well, but lacked strength. 410 and 416 (Martensitic Grain) provided the needed strength, but offered less general corrosion resistance. Turns out the catalyst was nickel content, but that’s another topic. The thought was, develop a grade that was half Austenite and half Martensite (Duplex), and enjoy the best of both worlds. The development of the original chemistry 2205 Duplex did just that. It fit the bill, but it was expensive and somewhat user unfriendly.

Years later, when the cost of elements used in the chemistry of the Duplex grades became prohibitive, those grades were pruned to the bone (reduced the expensive elements) to develop a new “More Economical” grade, Lean Duplex. Engineers were content to live with a much less effective product, in order to come up with a more affordable product. Nickel prices alone, had seen a ghastly increase at that time. The new LEAN DUPLEX, however, displayed an unexpected phenomenon; resistance to general corrosion and SCC was very near that of the original grade. Strength was also maintained; and, machinability was increased dramatically.

Today, LDX is most commonly used globally in tube and sheet form in construction of container vessels and conveyance items.

Lean Duplex (LDX)
Resists pitting and crevice corrosion similar to 316L
Resists Intergranular attack better than 304L or 316L
Resists Stress Corrosion Cracking better than 304L, 316L, 410, 416
Resists General Corrosion better than 304L, and 316L
Weldability – less restrictive than 2205

-Howard Thomas, July 6th 2021